Up to now, you could use VoIP applications on the iPhone only over Wi-Fi, which was quite restrictive with regards to the physical area in which you could do this. Now you can make and receive both local and worldwide calls over AT&T's 3G network, which spans over nearly every inhabited place. And for free. If both you and your contact are logged in on the same VoIP service, you can talk unlimitedly for free, thus bypassing the expensive mobile charges. Think of how much money you can save on international calls.
Now what can this mean for AT&T? In the short term, they will lose money but they could win on user amount as more people will join their 3G service with iPhone. Fewer people will pay the mobile calling minutes but more people will pay the 3G data plan.
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I wonder if the vonage app would work in India on a Blackberry? Or is it only for use in the US? And if so what charges would the user pay – regular cell phone minutes or data?